کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10142184 | 1646091 | 2019 | 31 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Cumulative effect of bimetallic alloy, conductive polymer and graphene toward electrooxidation of methanol: An efficient anode catalyst for direct methanol fuel cells
ترجمه فارسی عنوان
اثر تجمعی آلیاژهای دو فلزی، پلیمر رسانا و گرافن نسبت به الکترو اکسیداسیون متانول: یک کاتالیزور آنات کارآمد برای سلول های سوخت مستقیم متانول
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
چکیده انگلیسی
In this article, we report a wet reflux strategy for the synthesis of reduced graphene oxide (rGO)/polyaniline (PANI)/Pt-Pd composite, which was exploited as a potential anode catalyst with enhanced methanol oxidation capacity for direct methanol fuel cells (DMFCs). The construction of rGO/PANI/Pt-Pd involves two steps such as synthesis of PANI on GO and in-situ reduction of GO and metal precursors. The spherical shaped Pt-Pd particles with the average size of 3.5â¯nm are scattered throughout the surface of rGO/PANI, as observed from transmission electron microscope (TEM). PANI tailors the surface of rGO to allow the uniform scattering of Pt-Pd, which is beneficial for adsorption and decomposition of methanol. Besides, PANI generates strong interaction with Pt-Pd through nitride bond, thereby enhances the durability of composite. The cumulative features of rGO/PANI/Pt-Pd include active carbon support, extended architecture of electron conducting channels and number of methanol oxidation centers endows excellent DMFC power density of 117.45â¯mW/cm2 and concrete cell durability over 70â¯h. Therefore, the proposed rGO/PANI/Pt-Pd can be used to address various critical issues associated with commercial Pt/C catalyst.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 771, 15 January 2019, Pages 477-488
Journal: Journal of Alloys and Compounds - Volume 771, 15 January 2019, Pages 477-488
نویسندگان
Ravi Arukula, Mohanraj Vinothkannan, Ae Rhan Kim, Dong Jin Yoo,