کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10146285 | 1646400 | 2018 | 24 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Crosslinked PVDF-membranes for solvent resistant nanofiltration
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
Crosslinked poly(vinylidene difluoride) (PVDF) nanofiltration membranes were prepared and tested for solvent resistant nanofiltration (SRNF) and solvent tolerant nanofiltration (STNF, i.e. in solvent/water media) applications. The performance of the membranes was assessed by filtering ethanol (EtOH), iso-propanol (iPrOH), acetonitrile (ACN), dimethylformamide (DMF) or toluene (Tol) solutions containing Rose Bengal (RB), a 1017â¯Da solute. During these consecutive filtrations, the membranes displayed a solvent activation effect which was characterised by TEM, ATR-FTIR and via intermediate EtOH filtrations. This solvent activation resulted in a more permeable membrane (by a factor of 11), without loss in retention. Drying the membranes from MeOH resulted in a further increase of the RB retention in ACN and Tol to 98%. The stability of the membranes was characterised using SEM, weight loss analysis and ATR-FTIR. In STNF, a 99% RB retention was achieved from a 1:4 DMF/water mixture.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 566, 15 November 2018, Pages 223-230
Journal: Journal of Membrane Science - Volume 566, 15 November 2018, Pages 223-230
نویسندگان
Matthias Mertens, Cédric Van Goethem, Marloes Thijs, Guy Koeckelberghs, Ivo F.J. Vankelecom,