کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10150322 | 1662996 | 2018 | 35 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Rational design 3D nitrogen doped graphene supported spatial crosslinked Co3O4@NiCo2O4 on nickel foam for binder-free supercapacitor electrodes
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A three-dimensional spatial crosslinked Co3O4@NiCo2O4/N doped graphene (NG) growing on nickel foam has been prepared via hydrothermal reaction combining calcination. NiCo2O4 with hollow tubular structure is not only beneficial to storage Co3O4 nanoparticles, but also effectively maintains the neighboring NG nanosheets separated. With the help of this unique structure, the hybrid provides rich exposed electrochemical active sites and short-distance electron transport pathways. When directly serving as an electrode without using the binder for supercapacitors, Co3O4@NiCo2O4/NG/NF hybrid exhibits predominant specific capacitance (1094â¯Câ¯gâ1/2430â¯Fâ¯gâ1 at 1â¯Aâ¯gâ1), significant rate capability and persistent cycle life (retention of 93.7% even after 5000 continuous charge/discharge cycles) compared with other general electrode materials. The prepared asymmetric device provides a specific capacitance of 118.6â¯Fâ¯gâ1 at a current density of 1â¯Aâ¯gâ1, with a maximum energy density of 52.9â¯Wh kgâ1 (power density of 544â¯Wâ¯kgâ1). The device still has an energy density of up to 23.9â¯Wh kgâ1 at a maximum power density of 3630â¯Wâ¯kgâ1.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 290, 10 November 2018, Pages 12-20
Journal: Electrochimica Acta - Volume 290, 10 November 2018, Pages 12-20
نویسندگان
Ying Wang, Mingmei Zhang, Yuan Li, Tianjiao Ma, Hong Liu, Denghui Pan, Xinyu Wang, An Wang,