کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10261150 | 456584 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Batch kinetic study of sorption of methylene blue by perlite
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Batch sorption kinetics of methylene blue by perlite have been studied in terms of pseudo-first-order, pseudo-second-order and intra-particle diffusion models. The results showed that sorption process was best described by the pseudo-second-order model. The correlation coefficients, r2, obtained from pseudo-second-order model were higher than 0.98 under all the experiment conditions. The effects of agitation speed, initial dye concentration and solution temperature on kinetic parameters (sorption rate constant, initial sorption rate, equilibrium sorption capacity, etc.) are discussed. While the values of sorption rate constants (k2) and initial sorption rates (h) increased with increasing agitation speeds and solution temperatures, it was seen that the values of k2 decreased and the values of h increased with increased initial dye concentration. The values of equilibrium sorption capacity from pseudo-second order (q2) were in the best agreement with experimental data (qe) in each experimental condition. Moreover, the activation energy (Ea) of sorption calculated using the pseudo-second-order rate constants was found to be 10.31Â kJ/mol from an Arrhenius plot. The value of Ea indicated that sorption was controlled by an intra-particle diffusion mechanism as well as by pseudo-second-order kinetics.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 106, Issue 1, 28 January 2005, Pages 73-81
Journal: Chemical Engineering Journal - Volume 106, Issue 1, 28 January 2005, Pages 73-81
نویسندگان
Bilal AcemioÄlu,