کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10268554 | 459675 | 2011 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of ball-milling on the rate and cycle-life performance of graphite as negative electrodes in lithium-ion capacitors
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A commercial graphite is ball-milled and the pristine and ball-milled graphites are characterised for use as negative electrodes in lithium-ion capacitors (LICs). Ball milling graphite results in a decrease in discharge capacity when the charge rate is relatively slow, whereas, it leads to an increase in discharge capacity when the charge rate is high. When charged at 0.1 C, the discharge capacities of pristine, 3 h, 10 h and 30 h-milled materials at 6 C are 75, 69, 67 and 66% of theoretical capacity, respectively; however, when charged at 60 C, the discharge capacities of pristine, 3 h, 10 h and 30 h-milled materials, at 60 C, fall to 0.9, 13, 23 and 24% of theoretical capacity, respectively (theoretical capacity: 372 mAh gâ1, for LiC6 stoichiometry). This difference in the discharge rate capability behaviour of the pristine and ball-milled graphites with charge rate is attributed to the interplay of two different charge storage mechanisms: Li-ion intercalation and Li-ion adsorption that co-exist; but the later becomes more significant for milled samples. In terms of cycle-life performance, pristine and ball-milled graphites follow similar trends observed for their rate capability behaviour.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 56, Issue 27, 30 November 2011, Pages 9700-9706
Journal: Electrochimica Acta - Volume 56, Issue 27, 30 November 2011, Pages 9700-9706
نویسندگان
S.R. Sivakkumar, Adriyan S. Milev, A.G. Pandolfo,