کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10269541 | 459878 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Oxidation at boron doped diamond electrodes: an effective method to mineralise triazines
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Oxidation at boron doped diamond electrodes: an effective method to mineralise triazines Oxidation at boron doped diamond electrodes: an effective method to mineralise triazines](/preview/png/10269541.png)
چکیده انگلیسی
The electrochemical oxidation of cyanuric acid (CA) is examined by bulk electrolyses at boron doped diamond (BDD) electrode. The influence of operating conditions on the reaction trend is investigated and suitable conditions for oxidative demolition of CA are individuated. In particular a strong effect of current density and pH is evidenced, being neutral pH and high current the most favourable conditions to achieve CA mineralisation. The paper also presents the results from atrazine (2-Cl-4-ethylamino-6-isopropylamino-1,3,5-triazine) and 2-Cl-4,6-diammino-1,3,5-triazine oxidation at BDD anode. Triazine compounds are scarcely degraded even with powerful methods such as photocatalytic TiO2-mediated processes, being CA generally obtained as final product of their oxidation. Individuation of favourable conditions for CA demolition has allowed to find suitable conditions to mineralise also triazine compounds.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 50, Issue 9, 1 March 2005, Pages 1841-1847
Journal: Electrochimica Acta - Volume 50, Issue 9, 1 March 2005, Pages 1841-1847
نویسندگان
Anna Maria Polcaro, Annalisa Vacca, Michele Mascia, Simonetta Palmas,