کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10274747 | 461725 | 2011 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Separability of hydrogen from hydrogen-carbon dioxide mixture across silica-silicalite-1 film
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Colloidal silica particles, grown on a mesoporous silica layer using macroporous alumina substrate as a support, were used to separate hydrogen from carbon dioxide. The particles transformed into rectangular interlocking silicalite-1 structures with size approximately 8 Ã 4 Ã 4 μm, oriented epitaxially with film thickness of ca. 22 μm. The silicalite-1 particles grew in size due to the effect of structure directing agent (SDA), Oswald ripening and hydrothermal synthesis that promoted the growth of the colloidal particles into crystals. Permeation experiment using silicalite-1 showed that CO2 flux decreased and H2 flux increased with increase in temperature. The separability of H2 that was unity at the lower temperature became increased in value as the temperature was raised.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel Processing Technology - Volume 92, Issue 3, March 2011, Pages 428-432
Journal: Fuel Processing Technology - Volume 92, Issue 3, March 2011, Pages 428-432
نویسندگان
M.R. Othman, S.C. Tan, S. Bhatia, W.J.N. Fernando,