کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10275876 | 463406 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Kinetics of direct and substrate-mediated electron transfer of versatile peroxidase-modified graphite electrodes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Kinetics of direct and substrate-mediated electron transfer of versatile peroxidase-modified graphite electrodes Kinetics of direct and substrate-mediated electron transfer of versatile peroxidase-modified graphite electrodes](/preview/png/10275876.png)
چکیده انگلیسی
Electron transfer (ET) of versatile peroxidase (VP) was studied in the bioelectrocatalytic reduction reaction of H2O2 at peroxidase-modified graphite electrodes to obtain additional information on the kinetic characteristics of this novel ligninolytic peroxidase. Rotating disk electrodes (RDE) experiments were performed at 0Â V (vs. SCE) in two different buffers (tartrate buffer, pH 5.0; and citrate buffer, pH 3.0). From measurements of the mediated and mediatorless currents of H2O2 reduction at the RDE, the percentage of VP molecules involved in direct ET (â55%) was calculated. The peroxidase-modified electrodes were used for determination of the donor substrates in RDE mode, and the results were interpreted in terms of catalytic efficiencies.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 580, Issue 1, 15 June 2005, Pages 35-40
Journal: Journal of Electroanalytical Chemistry - Volume 580, Issue 1, 15 June 2005, Pages 35-40
نویسندگان
Florentina-Daniela Munteanu, Francisco J. Ruiz-Dueñas, Angel T. MartıÌnez, Artur Cavaco-Paulo,