Oxidation progress in an emulsion made from metmyoglobin and different triacylglycerols

► Model emulsion system monitoring specific lipid oxidation volatiles. ► Pure triacylglycerols and cod liver and salmon oil emulsified with metmyoglobin. ► Marker compounds of n-6 and n-3 development with time. ► Adductation and polymerisation of myoglobin due to reactive lipid degradation groups. ► PUFA unsaturation degree affected degradation, polymerisation and adductation.