کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10547547 | 964687 | 2005 | 19 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Pyrolysis of propane for CVI of pyrocarbon
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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چکیده انگلیسی
A detailed kinetic mechanism for the pyrolysis of propane is proposed, in order to reproduce the experimental gas phase species. This mechanism allows the reproduction of the formation of all the major products, identified experimentally, up to toluene. Validation of the mechanism has been performed by simulations and comparisons with experimental data. The agreement obtained is quite satisfactory considering the wide range of temperature and residence time studied. Main reaction paths have been determined by flux and sensitivity analyses, both for the reactant and for the important products like acetylene or propyne. The significant roles of radicals such as propargyl (C3H3) or cyclopentadienyl (C5H5) are discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Analytical and Applied Pyrolysis - Volume 73, Issue 2, June 2005, Pages 212-230
Journal: Journal of Analytical and Applied Pyrolysis - Volume 73, Issue 2, June 2005, Pages 212-230
نویسندگان
Isabelle Ziegler, R. Fournet, P.M. Marquaire,