کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10547837 | 965301 | 2011 | 13 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Polydimethylsiloxane-based permeation passive air sampler. Part I: Calibration constants and their relation to retention indices of the analytes
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A simple and cost effective permeation passive sampler equipped with a polydimethylsiloxane (PDMS) membrane was designed for the determination of time-weighted average (TWA) concentrations of volatile organic compounds (VOCs) in air. Permeation passive samplers have significant advantages over diffusive passive samplers, including insensitivity to moisture and high face velocities of air across the surface of the sampler. Calibration constants of the sampler towards 41 analytes belonging to alkane, aromatic hydrocarbon, chlorinated hydrocarbon, ester and alcohol groups were determined. The calibration constants allowed for the determination of the permeability of PDMS towards the selected analytes. They ranged from 0.026Â cm2Â minâ1 for 1,1-dichloroethylene to 0.605Â cm2Â minâ1 for n-octanol. Further, the mechanism of analyte transport across PDMS membranes allowed for the calibration constants of the sampler to be estimated from the linear temperature programmed retention indices (LTPRI) of the analytes, determined using GC columns coated with pure PDMS stationary phases. Statistical analysis using Student's t test indicated that there was no significant difference at the 95% probability level between the experimentally obtained calibration constants and those estimated using LTPRI for most analyte groups studied. This correlation allows the estimation of the calibration constants of compounds not known to be present at the time of sampler deployment, which makes it possible to determine parameters like total petroleum hydrocarbons in the vapor phase.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Chromatography A - Volume 1218, Issue 1, 7 January 2011, Pages 143-155
Journal: Journal of Chromatography A - Volume 1218, Issue 1, 7 January 2011, Pages 143-155
نویسندگان
Suresh Seethapathy, Tadeusz Górecki,