کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10559035 | 969209 | 2005 | 16 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The mechanism of formation of volatile hydrides by tetrahydroborate(III) derivatization: A mass spectrometric study performed with deuterium labeled reagents
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The mechanism of formation of volatile hydrides by tetrahydroborate(III) derivatization: A mass spectrometric study performed with deuterium labeled reagents The mechanism of formation of volatile hydrides by tetrahydroborate(III) derivatization: A mass spectrometric study performed with deuterium labeled reagents](/preview/png/10559035.png)
چکیده انگلیسی
A reaction model for hydride generation is proposed accounting for primary reactions giving rise to hydride formation through reaction intermediates, as well as side reactions involving D-H exchange and decomposition of reactive hydroboron species, reaction intermediates and final products. Hydrides are formed by direct hydrogen transfer from boron to the analyte atom, most likely through concerted mechanisms taking place via reaction intermediates.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part B: Atomic Spectroscopy - Volume 60, Issue 4, 30 April 2005, Pages 423-438
Journal: Spectrochimica Acta Part B: Atomic Spectroscopy - Volume 60, Issue 4, 30 April 2005, Pages 423-438
نویسندگان
Alessandro D'Ulivo, Zoltán Mester, Ralph E. Sturgeon,