کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10559927 969693 2005 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Simultaneous determination of antimony(III) and antimony(V) by UV-vis spectroscopy and partial least squares method (PLS)
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Simultaneous determination of antimony(III) and antimony(V) by UV-vis spectroscopy and partial least squares method (PLS)
چکیده انگلیسی
This paper describes a procedure for the speciation of antimony by UV-vis spectroscopy using pyrogallol as complexing agent. A partial least squares (PLS) regression was performed to resolve highly overlapping spectrophotometric signals obtained from mixtures of Sb(III) and Sb(V). The relative error in absolute value was less than 5% when concentrations of several mixtures were calculated. The minimum concentration determined was 3.96 × 10−5 mol dm−3 and 3.98 × 10−5 mol dm−3 for Sb(V) and Sb(III), respectively. The analysis of the possible effect of the presence of foreign ions in the solution was performed and the procedure was successfully applied to the speciation of antimony in pharmaceutical preparations and aqueous samples.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Talanta - Volume 68, Issue 1, 15 November 2005, Pages 67-71
نویسندگان
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