کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10559991 | 969698 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A new sensitive and selective fluorescence method for determination of chlorine dioxide in water using rhodamine S
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A new simple, selective and sensitive method for the determination of trace chlorine dioxide in water has been developed, based on the oxidation by chlorine dioxide to reduction the fluorescence of rhodamine dyes in ammonia-ammonium chloride buffer solution. Four rhodamine dyes systems such as rhodamine S, rhodamine G, rhodamine B and butyl-rhodamine B were tested. The rhodamine S system is the best, with a linear range of 0.0060-0.450 μg mLâ1 and a detection limit of 0.0030 μg mLâ1 ClO2. It was applied to the determination of chlorine dioxide in synthetic samples and real samples, with satisfactory results. This method has good selectivity, especially, other chlorine species such as chlorine, hypochlorite, chlorite and chlorate do not interfere the determination. The mechanism of fluorescence reduction was also considered.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Talanta - Volume 66, Issue 3, 30 April 2005, Pages 783-788
Journal: Talanta - Volume 66, Issue 3, 30 April 2005, Pages 783-788
نویسندگان
Zhi-Liang Jiang, Biao-Ming Zhang, Ai-Hui Liang,