کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10561585 969779 2005 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Anion recognition through novel C-thiophenecalix[4]resorcinarene: PVC based sensor for chromate ions
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Anion recognition through novel C-thiophenecalix[4]resorcinarene: PVC based sensor for chromate ions
چکیده انگلیسی
Novel ionophore, C-thiophenecalix[4]resorcinarene (I) has been synthesized and characterized by IR, NMR and C, H, N analysis. Poly(vinyl chloride) (PVC) based membranes of ionophore (I) using dibutylphthalate (DBP), dioctylphthalate (DOP), 1-chloronapthalene (CN), tris(2-ethylhexyl) phosphate (TEHP) and bis(2-ethylhexyl)sebacate (DOS) as plasticizing solvent mediators were prepared and used as CrO42− selective sensors. Of the various sensors prepared, the one with membrane composition 2:66:120 mg (I: PVC: DBP) exhibited the best performance. This sensor works well over a wide concentration range 5.6 × 10−6-1.0 × 10−1 M (detection limit ∼ 0.30 ppm) with Nernstian compliance (29.0 mV per decade) between pH 6.5-10.0 with a fast response time of ∼13 s. The selectivity coefficient values as determined by fixed interference method (FIM) indicate excellent selectivity for CrO42− ions over a large number of anions. The sensor exhibits adequate shelf-life ( ∼5 months) with good reproducibility (S.D. ± 0.2 mV). The sensor has been used in the potentiometric titration of chromate with Pb(II). Determination of chromium in electroplating waste using the sensor was successfully achieved.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Talanta - Volume 65, Issue 3, 15 February 2005, Pages 716-721
نویسندگان
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