کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10564476 | 970762 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Application of mid infrared spectroscopy and iPLS for the quantification of contaminants in lubricating oil
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The feasibility of using a narrow spectral range in the mid infrared region for a rapid and conclusive determination of contaminants (gasoline, ethylene glycol and water) in lubricating oil was investigated. A graphically-oriented local multivariate calibration modeling procedure called interval partial least-squares (iPLS) was applied to select a spectral range that provides the lowest prediction error, in comparison to the full-spectrum model. The region from 650 to 784Â cmâ1, attributed to aromatics, was selected for gasoline determination. The region from 918 to 1052Â cmâ1, for CâO stretching from glycol, was selected for ethylene glycol determination. Finally, the region from 3598 to 3732Â cmâ1, absorption from hydrogen bonded OH groups, was chosen for water determination. In the determinations, a root mean square error of prediction (RMSEP) of 0.34% for gasoline, 0.037% for ethylene glycol and 0.023% for water, were obtained after interval selection.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Vibrational Spectroscopy - Volume 37, Issue 1, 14 January 2005, Pages 27-32
Journal: Vibrational Spectroscopy - Volume 37, Issue 1, 14 January 2005, Pages 27-32
نویسندگان
Alessandra Borin, Ronei J. Poppi,