کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10564644 | 970853 | 2011 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Infrared and Raman studies of the anion ordering transitions in paramagnetic organometallic radical cation salts [Cp2Mo(dmit)]X (XÂ =Â PF6, SbF6)
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Temperature dependence of infrared and Raman spectra of the two isostructural salts [Cp2Mo(dmit)]PF6 and [Cp2Mo(dmit)]SbF6 is studied. At room temperature the physical properties of both compounds are very similar but at lower temperatures they undergo phase transitions associated with anion ordering, which are surprisingly different. The phase transitions in [Cp2Mo(dmit)]PF6 salt at T1Â =Â 120Â K and T2Â =Â 89Â K have no important influence on infrared and Raman spectra, while the phase transition in [Cp2Mo(dmit)]SbF6 salt at T1Â =Â 175Â K causes a splitting of Raman bands assigned to the CC stretching at about 1334Â cmâ1 and the in-plane Mo(dmit) ring deformation at about 353Â cmâ1, and also an infrared band at about 939Â cmâ1 related to the C-S stretching. The splitting of vibrational bands demonstrates a clear distortion of [Cp2Mo(dmit)]+ cations in the [Cp2Mo(dmit)]SbF6 salt. This molecular distortion is related to a lattice distortion providing thus a good argument for applicability of the compressible model of the anion ordering transition.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Vibrational Spectroscopy - Volume 55, Issue 2, March 2011, Pages 195-200
Journal: Vibrational Spectroscopy - Volume 55, Issue 2, March 2011, Pages 195-200
نویسندگان
Roman Åwietlik, Damian Jankowski, Marc Fourmigué, Kyuya Yakushi,