کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10568452 | 973429 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Nanocomposite electrolytes with fumed silica in poly(methyl methacrylate): thermal, rheological and conductivity studies
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Nanocomposite electrolytes with fumed silica in poly(methyl methacrylate): thermal, rheological and conductivity studies Nanocomposite electrolytes with fumed silica in poly(methyl methacrylate): thermal, rheological and conductivity studies](/preview/png/10568452.png)
چکیده انگلیسی
Composite polymer electrolytes (CPEs), were prepared by adding hydrophilic fumed silica in different proportions upto 5Â wt.% to gel polymeric electrolyte (GPE) comprising liquid electrolyte (1Â M LiClO4 in propylene carbonate) immobilized with 15Â wt.% poly(methyl methacrylate) (PMMA). The effect of fumed silica content in the CPEs on the ionic conductivity and viscosity over a wide temperature range was investigated. The resultant CPEs showed room temperature conductivity (Ï25) as high as 3.8Â mSÂ cmâ1 along with viscosity value of 3700Â P for 2Â wt.% SiO2 addition. Fumed silica addition both to the liquid electrolyte and to the GPE exhibits similar conductivity behaviour and this suggests a passive role of PMMA. The shear thinning behaviour, pointing towards easy processablity, high thermal stability and low volatility, makes these CPEs potential candidates as solid-like electrolytes for electrochemical devices.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 140, Issue 1, 10 January 2005, Pages 151-156
Journal: Journal of Power Sources - Volume 140, Issue 1, 10 January 2005, Pages 151-156
نویسندگان
Shahzada Ahmad, Sharif Ahmad, S.A. Agnihotry,