کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10571906 | 975187 | 2005 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Unexpected formation and structure elucidation of mer-[RuCl3(TMSO)(bpy)] derived from [H(TMSO)][trans-RuCl4(TMSO)2] under mild condition
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Unexpected formation and structure elucidation of mer-[RuCl3(TMSO)(bpy)] derived from [H(TMSO)][trans-RuCl4(TMSO)2] under mild condition Unexpected formation and structure elucidation of mer-[RuCl3(TMSO)(bpy)] derived from [H(TMSO)][trans-RuCl4(TMSO)2] under mild condition](/preview/png/10571906.png)
چکیده انگلیسی
The reaction of [H(TMSO)][trans-RuCl4(TMSO)2] with bpy in ethanol at room temperature resulted an unknown mer-[RuCl3(TMSO)(bpy)] (3) and a known cis-[RuCl2(TMSO)4] (4) (TMSO = tetramethylene sulfoxide, bpy = 2,2â²-bipyridine). The crystal structure of mer-[RuCl3(TMSO)(bpy)] (3) was determined by X-ray diffraction. The orange complex crystallizes in triclinic space group P1¯, a = 8.390(2) Ã
, b = 8.446(2) Ã
, c = 11.845(4) Ã
, α = 93.071(13)°, β = 91.228(11)°, γ = 93.831(13)°. The reaction is a new synthetic procedure for 3 and/or 3 and 4 at mild reaction condition from anionic complex involving concurrent substitution and redox reaction.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 358, Issue 3, 10 February 2005, Pages 854-857
Journal: Inorganica Chimica Acta - Volume 358, Issue 3, 10 February 2005, Pages 854-857
نویسندگان
Radhey S. Srivastava, Frank R. Fronczek,