کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10575159 977341 2005 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structure and reactivity of derivatives of dihalogenomethyl indium(III) halides, X2InCHX2 (X = Cl, Br, I)
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Structure and reactivity of derivatives of dihalogenomethyl indium(III) halides, X2InCHX2 (X = Cl, Br, I)
چکیده انگلیسی
The reactions of indium monohalides, InX with haloforms, CHX3, in 1,4-dioxane (diox), produce the X2In(diox)nCHX2 (X = Cl, Br, n = 1; X = I, n = 2) compounds. The ionic derivative [(C2H5)4N] [Cl3InCHCl2] was prepared and its crystal structure established by X-ray means. The dihalogenomethyl derivatives react with strong electrophiles suggesting dihalogenomethyl substituents of mild nucleophilic character, while the carbon atoms in the halogenomethyl derivatives are electrophilic.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 4, 14 February 2005, Pages 925-931
نویسندگان
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