کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10575202 | 977348 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Chiral “P-N-P” ligands, (C20H12O2)PN(R)PY2 [RÂ =Â CHMe2, YÂ =Â C6H5, OC6H5, OC6H4-4-Me, OC6H4-4-OMe or OC6H4-4-tBu] and their allyl palladium complexes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Chiral “P-N-P” ligands, (C20H12O2)PN(R)PY2 [RÂ =Â CHMe2, YÂ =Â C6H5, OC6H5, OC6H4-4-Me, OC6H4-4-OMe or OC6H4-4-tBu] and their allyl palladium complexes Chiral “P-N-P” ligands, (C20H12O2)PN(R)PY2 [RÂ =Â CHMe2, YÂ =Â C6H5, OC6H5, OC6H4-4-Me, OC6H4-4-OMe or OC6H4-4-tBu] and their allyl palladium complexes](/preview/png/10575202.png)
چکیده انگلیسی
Chiral “P-N-P” ligands, (C20H12O2)PN(R)PY2 [R = CHMe2, Y = C6H5 (1), OC6H5 (2), OC6H4-4-Me (3), OC6H4-4-OMe (4) or OC6H4-4-tBu (5)] bearing the axially chiral 1,1â²-binaphthyl-2,2â²-dioxy moiety have been synthesised. Palladium allyl chemistry of two of these chiral ligands (1 and 2) has been investigated. The structures of isomeric η3-allyl palladium complexes, [Pd(η3-1,3-R2â²-C3H3){κ2-(racemic)-(C20H12O2)PN(CHMe2)PY2}](PF6) (Râ²Â = Me or Ph; Y = C6H5 or OC6H5) have been elucidated by high field two-dimensional NMR spectroscopy. The solid state structure of [Pd(η3-1,3-Ph2-C3H3){κ2-(racemic)-(C20H12O2)PN(CHMe2)PPh2}](PF6) has been determined by X-ray crystallography. Preliminary investigations show that the diphosphazanes, 1 and 2 function as efficient auxiliary ligands for catalytic allylic alkylation but give rise to only moderate levels of enantiomeric excess.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 3, 28 January 2005, Pages 742-750
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 3, 28 January 2005, Pages 742-750
نویسندگان
Swadhin K. Mandal, G.A. Nagana Gowda, Setharampattu S. Krishnamurthy, Thomas Stey, Dietmar Stalke,