کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10601828 | 982355 | 2013 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A comparative study of cellulose nanofibrils disintegrated via multiple processing approaches
ترجمه فارسی عنوان
یک مطالعه تطبیقی نانوفیبریل سلولز با استفاده از رویکردهای پردازش چندگانه تخریب شده است
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کلمات کلیدی
نانوفیلترهای سلولز، پالایش، میکرو فلوئید سازی، پیشگیری از آنزیمی و شیمیایی،
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
چکیده انگلیسی
Various cellulose nanofibrils (CNFs) created by refining and microfluidization, in combination with enzymatic or 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) oxidized pretreatment were compared. The morphological properties, degree of polymerization, and crystallinity for the obtained nanofibrils, as well as physical and mechanical properties of the corresponding films were evaluated. Compared to refining, intense microfluidization contributed greater separation of nanofibril bundles, which led to an enhancement of mechanical strength and transparency for the resultant film. The selected enzymatic pre-treatments produced shortened fibers due to preferential hydrolysis of amorphous cellulose and, in combination with mechanical treatments, resulted in short and stiff cellulose nanocrystal (CNC)-like materials. Despite films from these CNC-like fibrils having inferior tensile strength, their tensile modulus and transparency were significantly improved compared to CNFs prepared without pre-treatment. The unique fiber morphology and high crystallinity potentially offer a green and ecologically friendly alternative for the preparation of CNCs and CNFs as part of an integrated biorefinery approach.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Polymers - Volume 97, Issue 1, 14 August 2013, Pages 226-234
Journal: Carbohydrate Polymers - Volume 97, Issue 1, 14 August 2013, Pages 226-234
نویسندگان
Yan Qing, Ronald Sabo, J.Y. Zhu, Umesh Agarwal, Zhiyong Cai, Yiqiang Wu,