کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10668809 | 1008471 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of densification processes on the properties of plasma-sprayed YSZ electrolyte coatings for solid oxide fuel cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Atmospheric plasma spraying (APS) was employed to deposit yttria-stabilized zirconia (YSZ) electrolyte for cermet supported tubular solid oxide fuel cells (SOFCs) to reduce manufacturing cost. A post-spray densification process was conducted for the APS-sprayed YSZ coating in order to achieve a required coating density for gas tightness and improved electrical conductivity. The deposition of the YSZ layer was carried out at ambient atmosphere using commercial ZrO2-8 wt.% Y2O3 powder. The densification of the YSZ coating was attained through impregnating yttrium and zirconium nitrate solutions into the porous coating, followed by thermal decomposition of nitrates within the pores of the coating through annealing treatment. The effects of impregnation number on gas permeability and electrical conductivity of the YSZ electrolyte have been examined. It was found that the gas permeability of the YSZ electrolyte layer after the densification treatment reaches a level of 2Ã10â7 cm4 gfâ1 sâ1, which is a necessary value for practical operation of SOFCs. The test cell yielded an open circuit voltage of 1.0 V at 930 °C. Furthermore, the anisotropy of the electrical conductivity of the YSZ coating is clearly elucidated by comparing the present result to the reported data. The electrical conductivity of the as-sprayed YSZ coating showed a value of 0.53 S mâ1 from the through-thickness direction at 900 °C. The post-densification treatment using nitrate solution improved the electrical conductivity of the YSZ layer by â¼30%.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Surface and Coatings Technology - Volume 190, Issue 1, 3 January 2005, Pages 60-64
Journal: Surface and Coatings Technology - Volume 190, Issue 1, 3 January 2005, Pages 60-64
نویسندگان
Chang-Jiu Li, Xian-Jin Ning, Cheng-Xin Li,