کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10714274 1025584 2012 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Investigation of the electrical properties of a new PPV derivative-based on a sandwich structure for opto-electronic applications
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
Investigation of the electrical properties of a new PPV derivative-based on a sandwich structure for opto-electronic applications
چکیده انگلیسی
The opto-electronic properties of native poly(p-phenylene vinylene) (PPV) were tuned by the confinement of the π-conjugation and the incorporation of a sulphur group as a spacer in order to obtain a blue-green emitting polymer (PPVS). The energy band gap of the PPVS thin film has been measured by UV-vis absorption spectroscopy and evaluated to 2.87 eV. Current-voltage characteristics and impedance spectroscopy measurements performed on sandwich structures [ITO/PPVS/Al] are used to elucidate the conduction mechanisms. The static electrical characterisations showed a space charge limited conduction (SCLC) and a conductivity with low power frequency behaviour characteristic of a hopping transport in disordered materials. The impedance spectra can be discussed in terms of an equivalent circuit model designed as a parallel resistor RP and capacitor CP network in series with a resistor RS. We extract numerical values of these parameters by fitting experimental data. Their evolution with bias voltages has shown that the SCLC mechanism is characterised by an exponential trap distribution.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physica B: Condensed Matter - Volume 407, Issue 7, 1 April 2012, Pages 1051-1054
نویسندگان
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