کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
11028292 | 1662996 | 2018 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Alkaline anion exchange membrane from poly(arylene ether ketone)-g-polyimidazolium copolymer for enhanced hydroxide ion conductivity and thermal, mechanical, and hydrolytic stability
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Alkaline anion exchange membrane from poly(arylene ether ketone)-g-polyimidazolium copolymer for enhanced hydroxide ion conductivity and thermal, mechanical, and hydrolytic stability Alkaline anion exchange membrane from poly(arylene ether ketone)-g-polyimidazolium copolymer for enhanced hydroxide ion conductivity and thermal, mechanical, and hydrolytic stability](/preview/png/11028292.png)
چکیده انگلیسی
A series of alkaline anion exchange membranes (AAEMs) are synthesized from poly (arylene ether ketone) -poly (vinyl-1-butylimidazolium) graft copolymers (PAEK-g-[PBVIm-OH]) with different [PBVIm-OH] cationic chain lengths. The chemical structure of the synthesized polymers is confirmed by 1H NMR and FTIR analysis. Several essential properties of AAEMs such as water uptake, hydroxide ion conductivity, and thermal, mechanical and dimensional stability for fuel cell applications are investigated and correlated to the ion cluster dimension examined by small-angle x-ray scattering. The PAEK-g-[PBVIm-OH]-based AAEMs show excellent thermal, mechanical, and dimensional stability, as they have the thermal degradation temperature of 250â¯Â°C, the tensile strength of 7.7â¯MPa and the planar swelling ratio of 12% at 40â¯Â°C. The hydroxide ion conductivity increases with increasing PBVIm-OH graft chain length. The AAEM membrane with the longest PBVIm-OH chain length (MW of â¼7000â¯gâ¯molâ1) exhibits the highest hydroxide conductivity of 0.00878â¯Sâ¯cmâ1 at 40â¯Â°C and the highest elongation of 206.7% in the hydrate state. The membrane electrode assembly fabricated from this membrane shows the highest power density of 22â¯mWâ¯cmâ2 at a current density of 55â¯mAâ¯cmâ2, which is very promising for fuel cell applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 290, 10 November 2018, Pages 544-555
Journal: Electrochimica Acta - Volume 290, 10 November 2018, Pages 544-555
نویسندگان
Anh Le Mong, Dukjoon Kim,