کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
11031149 1646072 2018 20 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Kinetic study of CH4 hydrate formation in the presence of tetrabutylphosphonium chloride (TBPC)
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Kinetic study of CH4 hydrate formation in the presence of tetrabutylphosphonium chloride (TBPC)
چکیده انگلیسی
Methane hydrate is considered as an excellent choice for transporting and storing natural gas. To improve the hydrate formation conditions, adding semiclathrate hydrate formers was strongly recommended. The major objective of this study was to investigate formation kinetics of tetrabutylphosphonium chloride (TBPC) + CH4 semiclathrate hydrate. Using isobaric kinetics measurement, the experiment was conducted systematically with various pressures (P: 4.0 MPa, 6.0 MPa), temperatures (282.1 K, 275.2 K, subcooling degree of 6 K), and salt concentrations (w: 0.05-0.30 mass fraction). Total gas consumption, normalized gas consumption, salt-to-hydrate conversion, rapid growth rate, and gas consumption percentage were calculated. The results revealed that for TBPC + CH4 hydrate salt-to-hydrate conversion was greatly affected by the concentration of TBPC. And the gas consumption percentage was found to reach 0.5 in the first 2 h for TBPC + CH4 hydrate. For designing gas storage process and fast hydrate formation process, the system with (w = 0.05, P = 6.0 MPa, subcooling degree of 6 K) and system with (w = 0.10, P = 6.0 MPa, T = 282.1 K) were recommended, respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 271, 1 December 2018, Pages 730-737
نویسندگان
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