Impedometric monitoring of the behavior of the supported liquid membrane in electromembrane extraction systems: An insight into the origin of optimized experimental parameters

• Electromembrane extraction has been monitored impedometrically.
• Impedance analysis provides useful information about the processes involved in EME.
• Experimental parameters of the extraction can be estimated from impedance analysis.

Electromembrane extraction (EME) was carried out using a novel instrumentation capable of impedometric monitoring of the system during the extraction. This instrumentation involves a classical two-electrode assembly fed by two time-resolved potential functions, the first for the extraction of analyte and the second for obtaining the impedance information. The impedometric analysis of the system was achieved by Laplace transformation of the current recorded during the extraction. It has been shown that the obtained impedance information can be converted to very useful knowledge about time dependence of double layer capacitance, kinetics of analyte depletion, total permeability of the SLM and the effect of experimental parameters on system behavior. It has also been shown that the impedance analysis is a powerful tool for the estimation of optimum experimental parameters without determination of analyte in the acceptor phase.

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