A novel approach for electromembrane extraction based on the use of silver nanometallic-decorated hollow fibers

• For the first time, a support containing metallic nanoparticles is used for EME.
• Polypropylene hollow fibers decorated with silver nanoparticles (AgNPs) were used as support.
• The presence of the NPs allows taking advantage of their singular properties.
• Procedure using the proposed support improves a previously published EME procedure for NSAIDs analysis.

A novel approach based on the use of nanometallic-decorated hollow fibers to assist electromembrane extraction is proposed. Microporous polypropylene hollow fibers, on which nanometallic silver was deposited, have been used for the first time as liquid membrane support in electromembrane extraction (EME). Different methods for the generation/deposition of silver nanoparticles (AgNPs) were studied. The best results were obtained with chemical reduction of silver nitrate using NaBH4 in aqueous solution followed by direct deposition on the hollow fibers. The extraction performance of the new supports was compared with a previously developed EME procedure used for the extraction of selected non-steroidal anti-inflammatory drugs (NSAIDs), resulting in an increase in the extraction ratio by a factor of 1.2–2 with a 30% reduction in the extraction time. The new nanometallic-decorated supports open new possibilities for EME due to the singular properties of nanometallic particles, including chemical fiber functionalization.

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