Amperometric detection of nitrite based on Dawson-type vanodotungstophosphate and carbon nanotubes

• A composite film was constructed by a vanodotungstophosphate and carbon nanotubes.
• The composite film showed fast electron transfer rate and high electrocatalytic activity of toward nitrite oxidation.
• The proposed sensor can amperometricially detect nitrite with high sensitivity and selectivity.

A nitrite sensor based on Dawson vanodotungstophosphates α2-K7P2VW17O62·18H2O (P2W17V) and carbon nanotubes (CNTs) was prepared by electrostatic layer-by-layer self-assembly technique. The sensor {PEI/PSS/[PDDA/P2W17V-CNTs]n} was characterized by UV–vis spectroscopy, atomic force microscopy (AFM), scanning electron microscopy (SEM) and X-ray photoelectron spectra (XPS). The electron transfer and sensing ability of this sensor were explored using cyclic voltammetry (CV) and electrochemical impedance spectra (EIS) technology. The results show that the incorporation of CNTs and P2W17V into the composite film endowed the modified electrode with fast transfer rate and high electrocatalytic activity towards oxidation of nitrite. This nitrite sensor with 10 bilayers has a broad linear range of 5 × 10−8 to 2.13 × 10−3 M, a low detection limit of 0.0367 μM (S N−1 = 3), a high sensitivity of 0.35 mA mM−1 NO2−, an excellent anti-interference property in the presence of other potential interfering species and a good stable. It was successfully employed for determination of nitrite in real towards.

A composite film has been constructed by vanodotungstophosphate α2-K7P2VW17O62·18H2O (P2W17V) and carbon nanotubes (CNTs) using the layer-by-layer self-assembly method. The incorporation of CNTs and P2W17V into the composite film endowed the modified electrode fast electron transfer rate and high electrocatalytic activity of toward nitrite oxidation. This nitrite sensor shows broad linear range, low detection limit, and high sensitivity and stability. Also it did not show any interference with other potential interfering species, and was successfully employed for determination of nitrite in real samples.Figure optionsDownload as PowerPoint slide