کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1166997 | 1491121 | 2012 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Electrochemical bisphenol A sensor based on N-doped graphene sheets Electrochemical bisphenol A sensor based on N-doped graphene sheets](/preview/png/1166997.png)
Bisphenol A (BPA), which could disrupt endocrine system and cause cancer, has been considered as an endocrine disruptor. Therefore, it is very important and necessary to develop a sensitive and selective method for detection of BPA. Herein, nitrogen-doped graphene sheets (N-GS) and chitosan (CS) were used to prepare electrochemical BPA sensor. Compared with graphene, N-GS has favorable electron transfer ability and electrocatalytic property, which could enhance the response signal towards BPA. CS also exhibits excellent film forming ability and improves the electrochemical behavior of N-GS modified electrode. The sensor exhibits a sensitive response to BPA in the range of 1.0 × 10−8–1.3 × 10−6 mol L−1 with a low detection limit of 5.0 × 10−9 mol L−1 under the optimal conditions. Finally, this proposed sensor was successfully employed to determine BPA in water samples with satisfactory results.
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► N-doped graphene sheets have catalytic activity towards the BPA oxidation.
► The biosensor based on N-doped graphene sheets and chitosan.
► This method was proposed for determination of BPA utilizing N-doped graphene sheets.
Journal: Analytica Chimica Acta - Volume 711, 20 January 2012, Pages 24–28