Synchronous determination of mercury (II) and copper (II) based on quantum dots-multilayer film

A sensitive sensor for mercury (II) and copper (II) synchronous detection was established via the changed photoluminescence of CdTe quantum dots (QDs) multilayer films in this work. QDs were deposited on the quartz slides to form QDs-multilayer films by electrostatic interactions with poly(dimethyldiallyl ammonium chloride) (PDDA). Hg2+ or Cu2+ could quench the photoluminescence of the QDs-multilayer films, and glutathione (GSH) was used to remove Hg2+ or Cu2+ from QDs-multilayer films due to strong affinity of GSH-metal ions, which resulted in the recovered photoluminescence of QDs-multilayer films. There are good linear relationships between the metal ions concentration and the photoluminescence intensity of QDs in the quenched and recovered process. It was found that the Stern–Volmer constants for Hg2+ are higher than that for Cu2+. Based on different quenching and recovery constant between Hg2+ and Cu2+, the synchronous detection of Hg2+ and Cu2+ can be achieved. The linear ranges of this assay were obtained from 0.005 to 0.5 μM for Hg2+ and from 0.01 to 1 μM for Cu2+, respectively. And the artificial water samples were determined by this method with satisfactory results, the recoveries for Hg2+ and Cu2+ ions were found in the range of 90.4–106.4%. To the best of our knowledge, it is the first report about the synchronous detection of Hg2+ and Cu2+ by using quenched and recovered photoluminescence of quantum dots multilayer films.

We developed a sensitive sensor for synchronous detection of Hg (II) and Cu (II) based on the quenchedand recovered PL intensity of QDs-multilayer films. Solutions containing Hg (II) or Cu (II) were used to quench the fluorescence of the QDs-multilayer films firstly. Then, glutathione (GSH) was used to remove Hg (II) or Cu (II) from the QDs-multilayer films due to stronger affinity of GSH-metal ions than that of QDs metal ions. Thus, the fluorescence of QDs-multilayer films was recovered.Figure optionsDownload as PowerPoint slideHighlights
► QDs-multilayer films were developed for synchronous detection of Hg (II) and Cu (II).
► Hg (II) and Cu (II) could quench the photoluminescence of the QDs-multilayer films.
► Glutathione was used to remove metal ions and recovery photoluminescence of QDs-multilayer films.