کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1168974 960614 2009 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Improving the detection of hydrogen peroxide of screen-printed carbon paste electrodes by modifying with nonionic surfactants
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Improving the detection of hydrogen peroxide of screen-printed carbon paste electrodes by modifying with nonionic surfactants
چکیده انگلیسی

Nonionic surfactants, such as Triton X-100 and Tween-20, were shown in this study to improve the electrocatalytic activity of screen-printed carbon paste electrodes (SPCE). The electrochemical response of SPCE to hydrogen peroxide increased 8–10-fold with the modification of nonionic surfactants. In addition, the glucose biosensors fabricated from nonionic surfactant-modified SPCE exhibited 6.4–8.6-fold higher response to glucose than that fabricated from unmodified SPCE. A concentration effect is proposed for nonionic surfactant to bring neutral reactants to the surface of electrode. Moreover, nonionic surfactant-modified SPCE exhibits a capability of repetitive usage and good reproducibility (R.S.D. < 5%) in the measurement of H2O2. Interestingly, the nonionic surfactant-modified SPCE exhibited an opposite effect to ascorbic acid, a common electroactive agent, which causes interference during clinical diagnosis. The differential responses of nonionic surfactant-modified SPCE to H2O2 and ascorbic acid suggest its potential in the development of biosensors for clinical diagnosis.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Analytica Chimica Acta - Volume 653, Issue 1, 19 October 2009, Pages 71–76
نویسندگان
, , ,