کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1169391 | 960633 | 2008 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Coupled in-tube and on-fibre solid-phase microextractions for cleanup and preconcentration of organic micropollutants from aqueous samples and analysis by gas chromatography–mass spectrometry Coupled in-tube and on-fibre solid-phase microextractions for cleanup and preconcentration of organic micropollutants from aqueous samples and analysis by gas chromatography–mass spectrometry](/preview/png/1169391.png)
Matrix interference removal is an important step when large volumes of aqueous samples are required to be processed to detect trace levels of analytes. A combination of two sample extraction methods has been used in this work with the aim of cleanup and preconcentration of analytes. For first objective, mild but preferential sorption of a range of analytes has been performed with in-tube solid-phase microextraction (SPME) using polytetrafluoroethylene (PTFE) tubing, and for the second, the eluate from in-tube SPME was subjected to on-fibre SPME using DVB/Caboxen/PDMS (30/50 μm) fibre. Knitting of PTFE tubing created secondary flow pattern that enhanced radial diffusion and retention of organic analytes. Up to 2 mg L−1 of a broad range of substances that are not extracted by PTFE include nitrogen containing aromatic heterocyclic compounds, anilines, phenols and certain organophosphorus pesticides, thus providing a clean extract using this method of sample preparation. The proposed combination of in-tube and on-fibre SPME produced a rectilinear calibration graph over 0.03–150 μg L−1 of a range of analytes using 60 mL of aqueous sample. The overall recovery of analytes was in the range 27–78%. The detection limits were between 6.1 and 21.8 ng L−1. The R.S.D. was in range 5.4–8.2% and 4.2–6.5% in the analysis of respectively 2 and 20 μg L−1 of analytes.
Journal: Analytica Chimica Acta - Volume 618, Issue 1, 16 June 2008, Pages 61–69