کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1171475 | 960721 | 2007 | 5 صفحه PDF | دانلود رایگان |
A method has been developed to determine acrylamide in aqueous matrices by using direct immersion solid-phase microextraction (SPME) coupled to gas chromatography–positive chemical ionization tandem mass spectrometry (GC–PCI-MS–MS) in the selected reaction monitoring (SRM) mode. The optimized SPME experimental procedures to extract acrylamide in water solutions were: use of a carbowax/divinylbenzene (CW/DVB)-coated fiber at pH 7, extraction time of 20 min and analyte desorption at 210 °C for 3 min. A detection limit of 0.1 μg L−1 was obtained. The linear range was 1–1000 μg L−1. The relative standard deviation was 10.64% (n = 7). The proposed analytical method was successfully used for the quantification of trace acrylamide in foodstuffs such as French fries (1.2 μg g−1) and potato crisps (2.2 μg g−1).
Journal: Analytica Chimica Acta - Volume 582, Issue 1, 16 January 2007, Pages 19–23