کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1172312 1491185 2006 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Self-assembled monolayer modified gold electrodes for traces Cu(II) determination
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Self-assembled monolayer modified gold electrodes for traces Cu(II) determination
چکیده انگلیسی

d,l-Penicillamine and thiodimethylglyoxime (TDMG) self-assembled monolayers (SAMs) on gold electrode were prepared and characterized by electrochemical measurements. The two sensors exhibit sensitive and selective response to Cu(II), both forming 2:1 complexes, the first one in acetic buffer and the second one in ammonia buffer.Copper determination at trace level (LOQ 0.2 and 0.3 μg/L for d,l-penicillamine and TDMG, respectively) is possible with both the electrodes as verified in tap, spring and sea water. The influence on copper determination of most common ions present in natural waters and of organic matter has been investigated. Accuracy was checked by recovery test on spiked samples.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Analytica Chimica Acta - Volume 557, Issues 1–2, 31 January 2006, Pages 45–51
نویسندگان
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