کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1179902 962808 2011 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Waveband selection for NIR spectroscopy analysis of soil organic matter based on SG smoothing and MWPLS methods
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Waveband selection for NIR spectroscopy analysis of soil organic matter based on SG smoothing and MWPLS methods
چکیده انگلیسی

Savitzky–Golay (SG) smoothing and moving window partial least square (MWPLS) methods were applied to the model optimization and the waveband selection for near-infrared (NIR) spectroscopy analysis of soil organic matter. The optimal single wavelength prediction bias (OSWPB) was used to evaluate the similarity of calibration set and prediction set, and a new division method for calibration set and prediction set was proposed. SG smoothing modes were expanded to 540 kinds. The specific computer algorithm platforms for optimization of SG smoothing mode combined with PLS factor and for MWPLS method with changeable parameters were built up. The optimal waveband for soil organic matter was 1926–2032 nm, the optimal smoothing mode was the 2nd order derivative, 6th degree polynomial, 45 smoothing points, the PLS factor, RMSEP and RP were 8, 0.260 (%) and 0.877 respectively. The prediction effect was obviously better than that in the whole spectral collecting region. To get stable results, all the optimization processes were based on the average prediction effect on 50 different divisions of calibration set and prediction set.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemometrics and Intelligent Laboratory Systems - Volume 107, Issue 1, May 2011, Pages 139–146
نویسندگان
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