کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1180353 962847 2008 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Inverse continuous wavelet transform in voltammetry
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Inverse continuous wavelet transform in voltammetry
چکیده انگلیسی

In this work, the application of the continuous wavelet transform (CWT) in connection with the inverse continuous wavelet transform (iCWT) in voltammetry is presented. In addition, optimization conditions are fulfilled by the use of the dedicated wavelet as a mother wavelet, defined on the base of an ideal voltammetric signal. It was proven that this rarely applied signal processing algorithm gives satisfactory results when used in both denoising and the removal of various shape baselines, as well as the separation of overlapping peaks. Numerous simulation examples, as well as three experimental tasks in which signal processing was necessary, are presented. The application of CWT followed by iCWT in voltammetric determination of Cr(VI) in natural water samples, the determination of Zn in pharmacological samples, and the analysis of Sb(III) concentrations in the presence of Cu(II) in suboptimal experimental conditions are described.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemometrics and Intelligent Laboratory Systems - Volume 94, Issue 2, 15 December 2008, Pages 131–139
نویسندگان
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