کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1181866 1491615 2016 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
An Innovative Approach to Sensitive Artificial Sweeteners Analysis by Ion Chromatography-Triple Quadrupole Mass Spectrometry
ترجمه فارسی عنوان
یک رویکرد نوآورانه برای تجزیه و تحلیل شفاف کننده های مصنوعی حساس با استفاده از اسپکترومتر جرم چهار بعدی کروماتوگرافی یونی
کلمات کلیدی
شیرین کننده های مصنوعی، ردیاب کروماتوگرافی یونی - طیف سنجی جرمی چهاربعدی سه گانه، آبهای زیرزمینی
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
چکیده انگلیسی

Artificial sweeteners (ASs) have gained more and more attention by environmental scientists because some of them such as acesulfame, have the potential to be the ideal tracers of domestic wastewater for environmental monitoring. In contrast to the existing methods of ASs, the analytical method of ASs as a novel tracer for environmental samples requires better sensitivity and selectivity to avoid matrix interference. A highly sensitive method for the simultaneous analysis of four frequently-used artificial sweeteners in water samples using solid phase extraction and ion chromatography triple quadrupole mass spectrometer with an electrospray ionization source in negative ion mode was developed. The separation effect of different columns was compared and a 2-mm ion chromatography column AS19 was chosen in the experiment. Chromatographic separation of the 4 artificial sweeteners was carried out in 9 min in isocratic elution mode using 60 mM sodium hydroxide (NaOH) as eluent. Different kinds of solid phase extraction (SPE) cartridges were evaluated to obtain satisfactory recoveries of all of the analytes. Merk LiChrolut EN (200 mg, 3 mL) was preconditioned with 2 mL of methanol, followed by 2 mL of H2O. About 200 mL of sample (pH < 2.0) was passed through the cartridge at a flow rate of 4 mL min−1, and then the cartridge was eluted with 2 mL of methanol. 2 mm suppresser (75 mA) was used to reduce the background noise and to inhibit the matrix interference. The limits of detection were below 5.0 ng L−1 for various artificial sweeteners based on 3-fold S/N. The recoveries of different matrices in the samples were 65%–120%. The method described here is time-saving, accurate and precise, and is suitable for monitoring artificial sweeteners in different water matrices. The method has also the potential to trace other contaminants in groundwater.

Graphical AbstractA highly sensitive method was developed for the simultaneous analysis of four frequently–used artificial sweeteners (AAs) in water samples by ion chromatography–triple quadrupole mass spectrometer with an electrospray ionization source in negative ion mode. Meanwhile the separation effect of different columns for AAs was compared and a 2-mm ion chromatographic column AS19 was chosen in the experiment.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Analytical Chemistry - Volume 44, Issue 3, March 2016, Pages 361–366
نویسندگان
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