Digital Asymmetric Waveform Isolation (DAWI) in a Digital Linear Ion Trap

Traditionally, in a quadrupole mass filter, ion isolation is achieved by scanning the rf and DC voltages with a fixed ratio. In this paper, we describe an innovative procedure implemented in a digitally driven linear ion trap termed digital asymmetric waveform isolation (DAWI) in which ion isolation is obtained by manipulation of the duty cycle of the rectangular waveforms. Variation of the waveform duty cycle allows introduction of a precisely defined DC quadrupole component into the main trapping field of the quadrupole ion filter. The DAWI method is completely controlled at software level and does not require any hardware modification.

Graphical AbstractAn innovative method that exploits the versatility of rectangular waveforms for precursor ion selection in a digital linear ion trap.Figure optionsDownload high-quality image (81 K)Download as PowerPoint slide