کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1196115 964454 2006 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Mass Spectrometric Separation and Quantitation of Overlapping Isotopologues. H2O/HOD/D2O and H2Se/HDSe/D2Se Mixtures
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Mass Spectrometric Separation and Quantitation of Overlapping Isotopologues. H2O/HOD/D2O and H2Se/HDSe/D2Se Mixtures
چکیده انگلیسی

Three conceptually different mathematical methods are presented for accurate mass spectrometric determination of H2O/HOD/D2O and H2Se/HDSe/D2Se concentrations from mixtures. These are alternating least-squares, weighted two-band target entropy minimization, and a statistical mass balance model. The otherwise nonmeasurable mass spectra of partially deuterated isotopologues (HOD and HDSe) are mathematically constructed. Any recorded isotopologue mixture mass spectra are then deconvoluted by least-squares into their components. This approach is used to study the H2O/D2O exchange reaction, and is externally validated gravimetrically. The H2O/D2O exchange equilibrium constant is also measured from the deconvoluted 70 eV electron impact GC/MS data (K = 3.85 ± 0.03).

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the American Society for Mass Spectrometry - Volume 17, Issue 7, July 2006, Pages 1028–1036
نویسندگان
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