کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1203198 | 965102 | 2011 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
On the optimization of the solid core radius of superficially porous particles for finite adsorption rate
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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چکیده انگلیسی
Packed chromatographic columns with the superficially porous particles (porous shell particles) guarantee higher efficiency. The theoretical equation of the Height Equivalent to a Theoretical Plate (HETP), for columns packed with spherical superficially porous particles, was used for the analysis of the column efficiency for finite rate of adsorption-desorption process. The HETP equation was calculated by the application of the moment analysis to elution peaks evaluated with the General Rate (GR) model. The optimal solid core radius for maximum column efficiency was estimated for a wide spectrum of internal and external mass transfer resistances, adsorption kinetic rate and axial dispersion. The separation power of the shell adsorbent for two component mixture, in analytical and preparative chromatography, was discussed. The conditions of the equivalence between the solutions of the General Rate model with slow adsorption kinetic and the Lumped Kinetic Model (LKM) or the Equilibrium Dispersive (ED) model were formulated.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Chromatography A - Volume 1218, Issue 7, 18 February 2011, Pages 951-958
Journal: Journal of Chromatography A - Volume 1218, Issue 7, 18 February 2011, Pages 951-958
نویسندگان
Krzysztof Kaczmarski,