کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1204424 | 965154 | 2010 | 10 صفحه PDF | دانلود رایگان |
A new generation polymeric ionic liquid (PIL), poly(1-4-vinylbenzyl)-3-hexadecylimidazolium bis[(trifluoromethyl)sulfonyl]imide (poly(VBHDIm+ NTf2−)), was synthesized and is shown to exhibit impressive selectivity towards the extraction of 12 polycyclic aromatic hydrocarbons (PAHs) from aqueous samples when used as a sorbent coating in direct-immersion solid-phase microextraction (SPME) coupled to gas chromatography (GC). The PIL was imparted with aromatic character to enhance π–π interactions between the analytes and the sorbent coating. For comparison purposes, a PIL with similar structure but lacking the π–π interaction capability, poly(1-vinyl-3-hexadecylimidazolium bis[(trifluoromethyl)sulfonyl]imide) (poly(HDIm+ NTf2−)), as well as a commercial polydimethylsiloxane (PDMS) sorbent coating were evaluated and exhibited much lower extraction efficiencies. Extraction parameters, including stir rate and extraction time, were studied and optimized. The detection limits of poly(VBHDIm+ NTf2−), poly(HDIm+ NTf2−), and PDMS coatings varied between 0.003–0.07 μg L−1, 0.02–0.6 μg L−1, and 0.1–6 μg L−1, respectively. The partition coefficients (log Kfs) of eight PAHs to the three studied fiber coatings were estimated using a static SPME approach. This study represents the first report of analyte partition coefficients to any PIL-based material.
Journal: Journal of Chromatography A - Volume 1217, Issue 40, 1 October 2010, Pages 6143–6152