کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1207891 | 1493723 | 2008 | 18 صفحه PDF | دانلود رایگان |
In this paper, we present a combination of a key-solute test based on retention and separation factors of large probe solutes (carotenoid pigments) and a quantitative structure-retention relationship analysis based on the retention factors of small probe solutes (aromatic compounds), both performed in supercritical fluid chromatography, to investigate the different chromatographic behaviour of octadecylsiloxane-bonded stationary phases of all sorts: classical, protected against silanophilic interactions or not, containing polar groups (endcapping groups or embedded groups). The results indicate that the two approaches chosen (carotenoid test and solvation parameter model) are complementary and provide precise information on the chromatographic behaviour of ODS phases. The applicability of the classification to the selection of stationary phases is evidenced with some examples of separations.
Journal: Journal of Chromatography A - Volume 1189, Issues 1–2, 2 May 2008, Pages 227–244