کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1209109 | 1493752 | 2007 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Chromatographic elution profile of an analyte involved in reversible chemical reaction of the type A + B â AB
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Chromatographic elution profile of an analyte involved in reversible chemical reaction of the type A + B â AB Chromatographic elution profile of an analyte involved in reversible chemical reaction of the type A + B â AB](/preview/png/1209109.png)
چکیده انگلیسی
The chromatographic peak profile of the analyte involved in a chemical reaction of the type A + B â AB is considered using method of the apparent adsorption isotherm. The apparent isotherms derived are nonlinear even under assumption of Henry isotherms of individual solutes. Nonlinearity of apparent adsorption isotherm results in peak distortion. The resulted chromatographic peak profile depends on several factors such as the equilibrium constant Kmob and Henry constants of the solutes. Simulated peak profiles of solutes involved in the chemical reaction are presented as illustration of influence of various factors.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Chromatography A - Volume 1150, Issues 1â2, 25 May 2007, Pages 112-116
Journal: Journal of Chromatography A - Volume 1150, Issues 1â2, 25 May 2007, Pages 112-116
نویسندگان
A. Yu Kanatyeva,