کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1210147 1493768 2006 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Adsorption behavior of hexafluorophosphate on selected bonded phases
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Adsorption behavior of hexafluorophosphate on selected bonded phases
چکیده انگلیسی

The adsorption behavior of ammonium hexafluorophosphate was studied on four HPLC columns packed with adsorbents of different ability for dispersive interactions using frontal chromatography with LC/MS detection in negative ESI mode. Hexafluorophosphate (PF6−) adsorption isotherms were measured from acetonitrile/water and methanol/water mixtures. Increased PF6− adsorption with increased acetonitrile content was found between 0 and 15% of acetonitrile in the eluent. Further increase of the acetonitrile concentration leads to an exponential decrease of PF6− adsorption. Methanol, on the other hand, causes a steady decrease of PF6− adsorption with increased organic concentration in the mobile phase.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Chromatography A - Volume 1119, Issues 1–2, 30 June 2006, Pages 43–50
نویسندگان
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