کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1234733 | 1495285 | 2008 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and spectral characterization of 2â²-hydroxy chalconate complexes of ruthenium(II) and their catalytic and biological applications
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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چکیده انگلیسی
The reactions of [RuHCl(CO)(B)(EPh3)2] (BÂ =Â EPh3 or pyridine; EÂ =Â P or As) and 2â²-hydroxychalcones in 1:2 ratio led to the formation of [Ru(CO)(B)(L)2] (BÂ =Â PPh3, AsPh3 or Py; LÂ =Â 2â²-hydroxychalcones). The new complexes have been characterized by analytical and spectral (IR, electronic and 1H NMR) data. They have been assigned an octahedral structure. The new complexes were found to catalyze the oxidation of alcohols to aldehydes using N-methylmorpholine-N-oxide as co-oxidant. All the new complexes were found to be active against bacteria such as E. coli, Salmonella typhi and fungi Aspergillus niger. The activity was compared with standard Streptomycin or Bavistin.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 70, Issue 5, October 2008, Pages 1222-1226
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 70, Issue 5, October 2008, Pages 1222-1226
نویسندگان
M. Muthukumar, P. Viswanathamurthi, K. Natarajan,