کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1239959 | 1495720 | 2013 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Hydride generation – in-atomizer collection of Pb in a quartz trap-and-atomizer device for atomic absorption spectrometry – an interference study Hydride generation – in-atomizer collection of Pb in a quartz trap-and-atomizer device for atomic absorption spectrometry – an interference study](/preview/png/1239959.png)
Interferences of selected hydride forming elements (As, Sb, Bi, Se and Sn) on lead determination by hydride generation atomic absorption spectrometry were extensively studied in both on-line atomization and preconcentration (collection) modes. The commonly used on-line atomization mode was found free of significant interferences, whereas strong interference from Bi was observed when employing the preconcentration mode with plumbane collection in a quartz trap-and-atomizer device. Interference of Bi seems to take place in the preconcentration step. Interference of Bi in the collection mode cannot be reduced by increased hydrogen radical amount in the trap and/or the atomizer.
► Interference study on Pb determination by in-atomizer trapping was performed for the first time.
► Bi was found as a severe interferent in the preconcentration mode (Pb:Bi ratio 1:100).
► No interference was found in the on-line atomization (no preconcentration).
► Bi interference occurs during preconcentration.
Journal: Spectrochimica Acta Part B: Atomic Spectroscopy - Volumes 79–80, 1 January–1 February 2013, Pages 77–81