کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1240914 1495734 2010 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Selective extraction of traffic-related antimony compounds for speciation analysis by graphite furnace atomic absorption spectrometry
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Selective extraction of traffic-related antimony compounds for speciation analysis by graphite furnace atomic absorption spectrometry
چکیده انگلیسی

Most traffic-related antimony air pollutants are derived from brake dust. Brake dust contains Sb2S3, used as a friction material in brake pads, and its high-temperature oxidation products, Sb2O3 or Sb2O4. Systematic investigations were carried out to find the most selective leaching conditions for these substances. First, solubility experiments of the pure potential compounds mentioned above were carried out. Then, the leaching of these compounds from home-made artificial dusts previously spiked with these compounds at the trace level was investigated. A 0.5 mol L−1 citric acid solution proved to leach the whole Sb2O3 content while extracting less than 10% Sb2S3 and no Sb2O4 at all. It was found that Sb2O3 and Sb2S3 traces were soluble in a 6 mol L−1 HCl solution, quantitatively and selectively. Graphite furnace atomic absorption spectrometry and hydride generation graphite furnace atomic absorption spectrometry methods were developed to determine the Sb content of the extracts. The proposed method proved to be applicable to settled dust containing traffic-related Sb compounds. The detection limits were 1.2 and 0.3 μg g−1 for leaching by citric acid and HCl solution, respectively, which were adequate for Sb content determination in the urban dust studied. The reproducibility of the method expressed as relative standard deviation was about 7%. The results showed that the concentration of leachable Sb was 40 μg g−1 in the settled dust of Budapest, about half of which corresponded to Sb2O3. The Sb2O4 content calculated as the difference of total and leachable fraction was about 10% with high uncertainty.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part B: Atomic Spectroscopy - Volume 65, Issues 9–10, September–October 2010, Pages 847–851
نویسندگان
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