کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1241261 969175 2008 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Laser-induced breakdown spectroscopy of carbon in helium and nitrogen at high pressure
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Laser-induced breakdown spectroscopy of carbon in helium and nitrogen at high pressure
چکیده انگلیسی

This work is devoted to the study of the gas pressure effect on the laser-induced breakdown spectroscopy signal intensity of carbon. Experiments are performed, using a 1064 nm Nd:YAG laser, with carbon solid samples placed inside a high pressure chamber filled with helium or nitrogen, the gas pressure varying from 1 to 80 atm. The signal intensity of the carbon line (247.86 nm) decreases with increasing pressure. As the plasma size strongly decreases with pressure, two collection optical setups are used, showing different raw results. To take into account the plasma size evolution with pressure, calculated corrections are applied to the collected light intensity. Carbon line emission is measured and corrected as a function of pressure in both gases. At 1 atm, the emission line is found to be greater in helium than in nitrogen by a factor of approximately 3, whereas the intensities in the two gases become close to each other at 80 atm.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part B: Atomic Spectroscopy - Volume 63, Issue 10, October 2008, Pages 1198–1204
نویسندگان
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