کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1242532 969637 2011 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A novel fused-silica capillary dropping mercury electrode with long drop-time and its application on determination of critical micelle concentration
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
A novel fused-silica capillary dropping mercury electrode with long drop-time and its application on determination of critical micelle concentration
چکیده انگلیسی
A novel long drop time mercury electrode has been constructed from common fused-silica capillary (50 μm I.D., 360 μm E.D.). Proposed device provides reproducible mercury drops with typical lifetime 40-120 s. The electrode was used for a set of electrocapillary measurements aimed at determination of critical micelle concentration of anionic surfactants by a convection controlled drop-time technique. A critical micelle concentration of sodium dodecyl sulfate 5.6 ± 0.4 mmol L−1 and 4.3 ± 0.4 mmol L−1 were obtained in 1 mmol L−1 and 5 mmol L−1 phosphate buffer (pH 7.0), respectively. The values were comparable to those obtained from conductometric measurements under the same conditions (7.0 ± 0.1 mmol L−1 and 5.2 ± 0.1 mmol L−1, respectively) and the difference was explained in accordance with theory of hemi-micelle formation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Talanta - Volume 84, Issue 1, 15 March 2011, Pages 187-191
نویسندگان
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